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The preparation, characterization, and catalytic performance of porous fibrous LaFeO

Zhifei Wu, Li Wang, Yixiao Hu, Hui Han, Xing Li, Ying Wang

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 967-975 doi: 10.1007/s11705-020-1922-0

Abstract: LaFeO perovskite with a porous fibrous structure was successfully synthesized using a sunflower seed

Keywords: NO oxidation     porous fibrous LaFeO<sub>3sub>     sunflower seed shell    

Sulfur-deficient CoNi<sub>2sub>S<sub>4sub> nanoparticles-anchored porous carbon nanofibers as bifunctional

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1707-1717 doi: 10.1007/s11705-023-2308-x

Abstract: Herein, aiming at the problems of high overpotential and slow kinetics in water splitting, N-doped porouscarbon nanofibers-coupled CoNi<sub>2sub>S<sub>4sub> nanoparticles are prepared as bifunctional electrocatalystIn the strategy, NaCl is used as the template to prepare porous carbon nanofibers with a large surface>2sub>S<sub>4sub> from 1.68 to 0.52 eV.The excellent performance results from the synergistic effect of porous structures, sulfur deficiency

Keywords: nanoparticle     sulfur vacancy     porous carbon nanofiber     transition metal sulfides     electrolysis    

Fabrication of three-dimensional porous La-doped SrTiO3 microspheres with enhanced visible light catalytic

Dong Yang, Xiaoyan Zou, Yuanyuan Sun, Zhenwei Tong, Zhongyi Jiang

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 440-449 doi: 10.1007/s11705-018-1700-4

Abstract: In this paper, three-dimensional porous La-doped SrTiO<sub>3sub> (LST) microspheres were prepared bya modified sol–gel method, in which the agarose gel/SrCO<sub>3sub> microsphere and La<sub>2sub>O<sub>3sub> were employed as the template and the La resource, respectively.The as-prepared LST microspheres exhibit a porous structure with a diameter of about 10 µm and a surfaceThe La element was doped into the crystal lattice of SrTiO<sub>3sub> by the substitution of La

Keywords: SrTiO<sub>3sub>     La3+ doping     porous microsphere     visible-light photocatalysis     Cr(VI) reduction    

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords: Rh<sub>2sub>O<sub>3sub>     CePO<sub>4sub>     N<sub>2sub>O decomposition    

A 3D porous WP2 nanosheets@carbon cloth flexible electrode for efficient electrocatalytic hydrogen evolution

Mingyu Pi, Xiaodeng Wang, Dingke Zhang, Shuxia Wang, Shijian Chen

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 425-432 doi: 10.1007/s11705-018-1726-7

Abstract:

Self-standing porous WP<sub>2sub> nanosheet arrays on carbon fiber cloth (WP<sub>2sub> NSs/CC)were synthesized and used as a 3D flexible hydrogen evolution electrode.Because of its 3D porous nanoarray structure, the WP<sub>2sub> NSs/CC exhibits a remarkable catalyticOur work makes the present WP<sub>2sub> NSs as a promising electrocatalyst for hydrogen evolution andprovides a way to design and fabricate efficient hydrogen evolution electrodes through 3D porous nano-arrays

Keywords: WP<sub>2sub>     nanosheet arrays     hydrogen evolution electrocatalyst     flexible electrode    

A Novel Hierarchically Lightweight Porous Carbon Derived from Egg White for Strong Microwave Absorption Article

Zonglin Liu, Xu Zhao, Liangliang Xu, Qingyu Peng, Xiaodong He

Engineering 2022, Volume 18, Issue 11,   Pages 161-172 doi: 10.1016/j.eng.2022.04.026

Abstract:

Egg custard is a common dish on the dining table and exhibits a uniform porous structure after freeze-dryingHerein, nitrogen in situ doped porous carbons (NPCs) and potassium-carbonate-modified NPCs (The unique morphologies of the porous carbon are inherited from the protein and include fibrous clustersAs a representative porous carbon, PNPC10-700 has multiple structures, including fibrous clusters, honeycombholes, and a porous skeleton.

Keywords: Microwave absorption     Porous carbon     Biomass     K<sub>2sub>CO<sub>3sub>    

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr<sub>2sub>O<sub>3sub> Systemwith Al<sub>2sub>O<sub>3sub> and Cr<sub>2sub>O<sub>3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Strategic Study of CAE 2004, Volume 6, Issue 6,   Pages 63-67

Abstract: lt;/sub>O<sub>3</sub> system with AI<sub>2</sub>O<sub>3</sub>and Cr<sub>2</sub>O<sub>3</sub> diluents were conducted, and the effects of reactionstarting temperature T<sub>O</sub>, diluents AI<sub>2</sub>O<sub>3</sub> and Cr<sub>2</sub>O<sub>3</sub> on the adiabatic combustion temperatureThe near linear relation between T<sub>0</sub> and T<sub>ad</sub> was obtained

Keywords: cermet     combustion synthesis     Al - Cr<sub>2sub>O<sub>3sub> system     thermodynamics     reaction model    

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

Frontiers in Energy 2023, Volume 17, Issue 5,   Pages 654-663 doi: 10.1007/s11708-023-0885-5

Abstract: In this paper, a broad spectrum responsive In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunctionis constructed by in-situ integrating Bi<sub>2sub>S<sub>3sub> with the In<sub>2sub>S<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction demonstrates a rate of 0.71 mmol/(g∙h), which is 2.2 and 1.7 times as much as those of In<sub>2sub>S<sub>3sub> (0.32 mmol/(g∙h) and Bi<sub>2sub>S<sub>3sub> (0.41 mmol/(g∙h)), respectively.

Keywords: photocatalytic hydrogen production     wide-spectrum response     metal sulfides     MOFs derivative     heterogeneous interfacial contact    

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al<sub>2sub>O<sub>3sub> with a small amount, wasintroduced into Pb/SiO<sub>2sub> catalyst in this study.It has been proved that Al<sub>2sub>O<sub>3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO<sub>2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O<sub>3sub> addition was also proposed.

Keywords: Pb/SiO<sub>2sub>     Al<sub>2sub>O<sub>3sub>     propane dehydrogenation     propene     stability    

acid anions on highly efficient Ce-based catalysts for selective catalytic reduction of NO with NH<sub>3sub>

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1399-1411 doi: 10.1007/s11705-023-2345-5

Abstract: <sub>3sub>) were synthesized and used for the selective catalytic reduction (SCR) of NO by NH<sub>3NH<sub>3sub>-SCR performances were conducted in the temperature range of 80 to 400 °C.> Ce<sub>2sub>(SO<sub>4sub>)<sub>3sub>, which is in agreement with their abilities of NH<sub>3sub>4sub>3, VO<sub>4sub>3 and SO<sub>4sub>2–2sub> for Ce<sub>2sub>(SO<sub>4sub>)<sub>3sub>.

Keywords: CePO<sub>4sub>     CeVO<sub>4sub>     Ce<sub>2sub>(SO<sub>4sub>)<sub>3sub>     selective catalytic reduction    

Fabrication of coconut shell-derived porous carbons for CO adsorption application

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 8,   Pages 1122-1130 doi: 10.1007/s11705-022-2292-6

Abstract: Biomass-derived porous carbons have been considered as the most potential candidate for effective CO<sub>2sub> adsorbent thanks to being widely-available precursor and having highly porous structure andHowever, the biomass-derived porous carbons still suffer from the poor optimization process in terms>2sub>/N<sub>2sub> selectivity.>2sub> capture performance, indicating coconut shell-derived porous carbon has a considerable potential

Keywords: porous carbons     CO<sub>2sub> adsorption     KOH activation     single step reaction     biomass    

On the monolayer dispersion behavior of Co<sub>3sub>O<sub>4sub> on HZSM-5 support: designing applicable

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1741-1754 doi: 10.1007/s11705-023-2332-x

Abstract: Based on monolayer dispersion theory, Co<sub>3sub>O<sub>4sub>/ZSM-5 catalysts with different loadingsCo<sub>3sub>O<sub>4sub> can spontaneously disperse on HZSM-5 support with a monolayer dispersionBelow the monolayer dispersion threshold, Co<sub>3sub>O<sub>4sub> is finely dispersed as sub-monolayersHowever, the formation of crystalline Co<sub>3sub>O<sub>4sub> above the capacity is harmful to thecapacity amount of Co<sub>3sub>O<sub>4sub> onto HZSM-5 support.

Keywords: Co<sub>3sub>O<sub>4sub>/ZSM-5     NO<sub>xsub>-SCR by NH<sub>3sub>     monolayer dispersionthreshold effect     surface acid sites     surface active O<sub>2sub> anions    

CO<sub>2sub> methanation and co-methanation of CO and CO<sub>2sub> over Mn-promoted Ni/Al<sub>2sub>O<sub>3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2,   Pages 273-280 doi: 10.1007/s11705-016-1563-5

Abstract: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

Keywords: Mn promotion     nickel catalysts     CO<sub>2sub> methanation     co-methanation of CO and CO<sub>2sub>    

Is atmospheric oxidation capacity better in indicating tropospheric O formation?

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 5, doi: 10.1007/s11783-022-1544-5

Abstract: ListItem>

● This study summarizes and evaluates different approaches that indicate O<sub>3sub> formation.

Keywords: O<sub>3sub>     AOC     O<sub>3sub> formation regime    

Spray Preparation, Microstructure and Properties of Al<sub>2sub>O<sub>3sub>-M<sub>xsub>O Hard -

Wang Biao,Wang Yudong,Li Huiling,Zhang Zihua

Strategic Study of CAE 2002, Volume 4, Issue 9,   Pages 75-80

Abstract: carbon steel substrate, base coating of nickel-coated aluminium and intermediate coating of 50% Al<sub>2sub>O<sub>3sub> + 50% Ni were prepared by means of oxyacetylene spray, and final coating of Al<sub>2sub>O<sub>3sub> ~ M<sub>xsub>O<sub>ysub> was prepared by means of plasma spray.of 60% (mass) sulphuric acid with 60 % concentration, and 40% (mass) phosphoric ore powder, the Al<sub>2sub>O<sub>3sub> ~ M<sub>xsub>O<sub>ysub> coating resistance to corrosion and wear, is 7.46

Keywords: Al<sub>2sub>O<sub>3sub>-M<sub>xsub>O<sub>ysub>     coating     plasma     resistance to corrosion     resistance    

Title Author Date Type Operation

The preparation, characterization, and catalytic performance of porous fibrous LaFeO

Zhifei Wu, Li Wang, Yixiao Hu, Hui Han, Xing Li, Ying Wang

Journal Article

Sulfur-deficient CoNi<sub>2sub>S<sub>4sub> nanoparticles-anchored porous carbon nanofibers as bifunctional

Journal Article

Fabrication of three-dimensional porous La-doped SrTiO3 microspheres with enhanced visible light catalytic

Dong Yang, Xiaoyan Zou, Yuanyuan Sun, Zhenwei Tong, Zhongyi Jiang

Journal Article

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

A 3D porous WP2 nanosheets@carbon cloth flexible electrode for efficient electrocatalytic hydrogen evolution

Mingyu Pi, Xiaodeng Wang, Dingke Zhang, Shuxia Wang, Shijian Chen

Journal Article

A Novel Hierarchically Lightweight Porous Carbon Derived from Egg White for Strong Microwave Absorption

Zonglin Liu, Xu Zhao, Liangliang Xu, Qingyu Peng, Xiaodong He

Journal Article

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr<sub>2sub>O<sub>3sub> Systemwith Al<sub>2sub>O<sub>3sub> and Cr<sub>2sub>O<sub>3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Journal Article

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

Journal Article

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Journal Article

acid anions on highly efficient Ce-based catalysts for selective catalytic reduction of NO with NH<sub>3sub>

Journal Article

Fabrication of coconut shell-derived porous carbons for CO adsorption application

Journal Article

On the monolayer dispersion behavior of Co<sub>3sub>O<sub>4sub> on HZSM-5 support: designing applicable

Journal Article

CO<sub>2sub> methanation and co-methanation of CO and CO<sub>2sub> over Mn-promoted Ni/Al<sub>2sub>O<sub>3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Journal Article

Is atmospheric oxidation capacity better in indicating tropospheric O formation?

Journal Article

Spray Preparation, Microstructure and Properties of Al<sub>2sub>O<sub>3sub>-M<sub>xsub>O Hard -

Wang Biao,Wang Yudong,Li Huiling,Zhang Zihua

Journal Article